Industry: petrochemical · TD-NMR

Hydrogen content of fuels

The proton signal is directly proportional to hydrogen content, an important quality parameter for jet fuel, diesel and other middle distillates, measured without solvents.

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What it tells you

A quality parameter that links to combustion

The hydrogen content of a fuel is linked to its combustion properties, such as the energy it releases and its tendency to form smoke. It is therefore an important parameter for jet fuel, diesel and other middle distillates. Every hydrogen atom in the sample contributes the same signal, so the signal is directly proportional to the hydrogen content.

Three steps: fill a tube with the fuel, measure without solvent, and read the hydrogen content
Measuring the hydrogen content of a fuel. Schematic illustration.
Typical samples

Where it is used

  • Aviation turbine fuel
  • Diesel, gas oil and other middle distillates
  • Light distillates and heavier residual products, depending on the method

Typical tasks are quality control of refinery and blending streams, checking deliveries, and following the effect of a process change on the product.

How it works

Signal proportional to hydrogen

A sample of the fuel is placed in a tube as it is and the proton signal is measured. A calibration with samples of known hydrogen content, measured with the reference method, turns the signal into a percentage. The measurement is quick and can be automated for series of samples.

Calibration line of NMR signal against the hydrogen content by a reference method, with a new sample read from the line
Calibration of hydrogen content. Schematic illustration, not measured data.
Methods and standards

Recognised test methods

  • ASTM D3701 for aviation turbine fuels
  • ASTM D4808 for light and middle distillates, gas oils and residual products
  • ASTM D7171 for middle distillates

These are low-resolution NMR methods for hydrogen content. Which of them applies depends on the product and on your specification, and this should be confirmed before the method is set up.

Why time-domain NMR

What it adds

  • No solvents, no dilution and no waste
  • A short measurement time, suitable for control of streams in a refinery laboratory
  • Non-destructive, so the sample is not changed
  • Automation for many samples
Good to know

Points that matter in practice

  • Control the temperature of the sample, since it affects the signal and the density of the fuel
  • Samples that lose light components by evaporation should be kept in closed containers
  • Check the calibration regularly with reference fuels
  • Compliance with a standard has to be confirmed for the exact instrument, software version and method that you use
How MSY Consulting helps

From your fuels to a routine method

Send or bring representative samples. MSY Consulting runs feasibility measurements, plans the calibration against your reference, and trains your team until the method is part of your routine.

Contact

Let's talk about your application

Send an email describing your instrument and your application, and you will get a reply.

contact@msyconsulting.eu

MSY CONSULTING SAS · Wissembourg, France · LinkedIn